TY  - INPR
U1  - Preprint
A1  - Morgenstern, Annika
A1  - Viriato, Lucas
A1  - Ortmann, Frank
A1  - Bickmann, Christopher
A1  - Hertling, Lukas
A1  - Weber, Dominik
A1  - Zahn, Dietrich R. T.
A1  - Hiller, Karla
A1  - Unwerth, Thomas von
A1  - Schondelmaier, Daniel
A1  - Salvan, Georgeta
T1  - Organic Hydrogen Sensors for Potential Use in Safety-Critical Environments
N2  - Accurate monitoring of the hydrogen concentration is critical for optimizing fuel cell performance, minimizing purge losses, and reducing long-term degradation. Conventional hydrogen sensors often rely on catalytic materials and face limitations such as the need of oxygen purging when operated in fuel cell environments. Here, we report the discovery of a novel hydrogen-sensing mechanism based on organic molecules, without the use of catalytic metals. The sensor is based on a typical vertical stack geometry, containing Alq3 as active organic material. Upon exposure to hydrogen, the device shows an increase in resistivity, yielding a reliable sensor signal that varies linearly with hydrogen concentration, temperature, and humidity, and exhibits a relative response of up to 3.5 % at 100 %vol hydrogen. By exposing the sensor to an external magnetic field, the rise and fall times of the sensor response were found to be tunable. This novel organic sensor demonstrates sensitivity across a wide range of hydrogen concentrations under fuel cell-relevant conditions and beyond. This new class of hydrogen sensors with high miniaturization potential and cost efficiency paves the way for real-time hydrogen monitoring and advanced control strategies in fuel cells, the chemical industry, or energy storage applications.
AB  - Accurate monitoring of the hydrogen concentration is critical for optimizing fuel cell performance, minimizing purge losses, and reducing long-term degradation. Conventional hydrogen sensors often rely on catalytic materials and face limitations such as the need of oxygen purging when operated in fuel cell environments. Here, we report the discovery of a novel hydrogen-sensing mechanism based on organic molecules, without the use of catalytic metals. The sensor is based on a typical vertical stack geometry, containing Alq3 as active organic material. Upon exposure to hydrogen, the device shows an increase in resistivity, yielding a reliable sensor signal that varies linearly with hydrogen concentration, temperature, and humidity, and exhibits a relative response of up to 3.5 % at 100 %vol hydrogen. By exposing the sensor to an external magnetic field, the rise and fall times of the sensor response were found to be tunable. This novel organic sensor demonstrates sensitivity across a wide range of hydrogen concentrations under fuel cell-relevant conditions and beyond. This new class of hydrogen sensors with high miniaturization potential and cost efficiency paves the way for real-time hydrogen monitoring and advanced control strategies in fuel cells, the chemical industry, or energy storage applications.
Y1  - 2026
U6  - https://doi.org/10.48550/arXiv.2602.04434
DO  - https://doi.org/10.48550/arXiv.2602.04434
SP  - 33
PB  - arXiv
ER  -